BENZOYL CHLORIDE

'Benzoyl chloride', also known as benzenecarbonyl chloride, is a colourless, fuming liquid, C₆H₅COCl, with an irritating odour. In the laboratory it may be prepared by distilling benzoic acid (C₆H₅COOH) with phosphorus pentachloride in anhydrous conditions. This replaces the hydroxy group of benzoic acid with a chlorine atom. This chlorination can also be accomplished using thionyl chloride. On a larger scale it is prepared by chlorinating benzaldehyde.
This substance is used as an intermediate chemical in the preparation of dyes, perfumes, peroxides, pharmaceuticals, and resins. It is also used in photography; as gasoline gum inhibitors, and in the manufacture of synthetic tannins. It was formerly employed as an irritant gas in chemical warfare.

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Reactions

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Reactions

Like all other acyl chlorides, benzoyl chloride can also react with alcohols and amines to give the corresponding esters and amides, just as any acyl chloride can.
Benzoyl chloride is easily hydrolyzed; it reacts with water to produce hydrochloric acid and benzoic acid.
: PhCOCl + H₂O → PhCOOH + HCl

External links

★ International Chemical Safety Card 1015