BORON CARBIDE
| Boron carbide | |
|---|---|
| General | |
| Systematic name | Boron carbide |
| Other names | Tetrabor B4-C B4C Black Diamond |
| Molecular formula | B4C |
| Molar mass | 55.255 g/mol |
| Appearance | Black powder. |
| CAS number | |
| Properties | |
| Density and phase | 2.52 g/cm3, solid. |
| Solubility in water | Insoluble. |
| Melting point | 2350 °C (2623.15 K) |
| Boiling point | >3500 °C (>3773.15 K) |
| Structure | |
| Molecular shape | ? |
| Coordination geometry | ? |
| Crystal structure | Rhombohedral |
| Dipole moment | ? D |
| Hazards | |
| MSDS | >External MSDS] |
| Main hazards | Harmful, irritant. |
| NFPA 704 | |
| Flash point | Non-flammable. |
| R/S statement | R: , , . S: , . |
| RTECS number | ? |
| Supplementary data page | |
| Structure and properties | ''n'', εr, etc. |
| Thermodynamic data | Phase behaviour Solid, liquid, gas |
| Spectral data | UV, IR, NMR, MS |
| Related compounds | |
| Other anions | ? |
| Other cations | ? |
| Related compounds | Boron nitride |
| Except where noted otherwise, data are given for materials in their standard state (at 25°C, 100 kPa) | |
'Boron carbide' (chemical formula B4C) is an extremely hard ceramic material used in tank armor, bulletproof vests, and numerous industrial applications. With a hardness of 9.3 on the mohs scale, it is the fifth hardest material known behind boron nitride, diamond, ultrahard fullerite, and aggregated diamond nanorods.
Discovered in the 19th century as a by-product of reactions involving metal borides, it was not until the 1930s that the material was studied scientifically. Boron carbide is now produced industrially by the carbo-thermal reduction of B2O3 (boron oxide) in an electric arc furnace.
Its ability to absorb neutrons without forming long lived radionuclides makes the material attractive as an absorbent for neutron radiation arising in nuclear power plants. Nuclear applications of boron carbide include shielding, control rod and shut down pellets.
| Contents |
| Applications |
| References |
| External links |
Applications
★ Personal and vehicle anti-ballistic armor plating, small-arms protective inserts.
★ Grit blasting nozzles.
★ High-pressure water jet cutter nozzles.
★ Scratch and wear resistant coatings.
★ Cutting tools and dies.
★ Abrasives such as used in grinding wheels.
★ Neutron absorber and control rod material in nuclear reactors.
References
★ Carbide, Nitride and Boride Materials Synthesis and Processing ISBN 0-412-54060-6
External links
★ National Pollutant Inventory - Boron and compounds
★ NIST Chemistry Database Entry for Boron Carbide
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