A 'calorie' is a unit of measurement for
energy. ''Calorie'' is
French and derives from the
Latin ''calor'' (heat). In most fields, it has been replaced by the
joule, the
SI unit of energy. However, the kilocalorie or Calorie (capital "C") remains in common use for the amount of
food energy.
Definitions for calorie fall into 3 classes:
★ The 'small calorie' or 'gram calorie' approximates the energy needed to increase the temperature of 1
gram of
water by 1
°C. This is about 4.184
joules.
★ The 'large calorie' or 'kilogram calorie' approximates the energy needed to increase the temperature of 1
kg of water by 1 °C. This is about 4.184
kJ, and exactly 1000 small calories.
★ The 'mega calorie' or 'ton calorie' approximates the energy needed to increase the temperature of 1
tonne of water by 1 °C. This is about 4.184
MJ, and exactly 1000 large calories.
In scientific contexts, the name "calorie" refers strictly to the gram calorie, and this unit has the symbol 'cal'.
SI prefixes are used with this name and symbol, so that the kilogram calorie is known as the "kilocalorie" and has the symbol 'kcal'. In non-scientific contexts the kilocalorie is often referred to as a Calorie (capital "C"), or just a calorie, and it has to be inferred from the context that the small calorie is not intended.
The conversion factor among calories and joules is numerically equivalent to the
specific heat capacity of liquid
water (in
SI units).
:1 cal
INT = 4.1868 J (1 J = 0.23885 cal
IT)
:1 cal
th = 4.184 J (1 J = 0.23901 cal
th)
:1 cal
15 = 4.18580 J (1 J = 0.23890 cal
15)
Versions
The energy needed to increase the temperature of 1
g of water by 1 Celsius varies depending on the starting temperature, and is in any case difficult to measure precisely. Accordingly there have been several definitions of the calorie:
★ 15 °C calorie: the amount of energy required to warm 1 g of air-free water from 14.5 °C to 15.5 °C at a constant pressure of 101.325 kPa (1
atm). Experimental values of this calorie ranged from 4.1852 J to 4.1858 J. The
CIPM in 1950 published a mean experimental value of 4.1855 J, noting an uncertainty of 0.0005 J.
★ 20 °C calorie: the amount of energy required to warm 1 g of air-free water from 19.5 °C to 20.5 °C at a constant pressure of 101.325 kPa (1
atm). This is about 4.182 J.
★ 4 °C calorie: the amount of energy required to warm 1 g of air-free water from 3.5 °C to 4.5 °C at a constant pressure of 101.325 kPa (1
atm).
★ Mean calorie: 1/100 of the amount of energy required to warm 1 g of air-free water from 0 °C to 100 °C at a constant pressure of 101.325 kPa (1
atm). This is about 4.190 J
★ International Steam Table Calorie (1929): (1/860)
W h = (180/43) J exactly. This is approximately 4.1860 J.
★ International Steam Table Calorie (1956): 1.163 m
W h = 4.1868 J exactly. This definition was adopted by the Fifth International Conference on Properties of Steam (London, July 1956).
★ Thermochemical calorie: 4.184 J exactly.
★ IUNS calorie: 4.182 J exactly. This is a definition implied by the Committee on Nomenclature of the International Union of Nutritional Sciences (''date and reference needed'').
The two perhaps most popular definitions used in older literature are the "15 °C calorie" and the "thermochemical calorie". Since the many different definitions are a source of confusion and error, all calories are now
deprecated in favour of the
SI unit for heat and energy: the
joule (J).
Nutrition
In
nutrition, the difference between these calorie definitions is of no practical relevance. This is because nutritional calories are not measured amounts of energy, but are calculated from food composition. Such calculations use internationally agreed
conventional conversion factors, which are generously rounded values that roughly approximate the average energy density of a large number of different food samples. The exact composition of agricultural products varies far more than the 0.1% difference between the above definitions of the calorie as a physical energy measure.
Human fat tissue contains about 87%
lipids, so that 1 kg of body-fat tissue has roughly the caloric energy of 870 g of pure fat, or 7800 kcal. In principle one has to create a 7800 kcal deficit or surplus between energy intake and use to lose or gain 1 kg of body-fat. (or 3500 kcal per
pound).
[1] However, if one eats 7800 kcal more than the body needs, one won't necessarily gain 1 kg of fat, since muscle and other tissues may be built. The same way, if one eats 7800 kcal less than their maintenance level, they may not lose 1 kg of fat, since muscle and sugars may be metabolized to generate energy.
Trivia
★
Unicode has a symbol for "cal": (㎈), but this is just a legacy compatibility code to accommodate the old
code pages in certain Asian languages.
★ The conventional value chosen to define one ton of TNT is equal to 1
billion thermochemical calories: 1 t
TNT ≡ 1 × 10
9 cal
th. The actual energy liberated from the explosion is somewhat more; see
megaton.
See also
★
Empty calorie
★
Heat of combustion
★
ISO 31-4
★
Nutrition
References
1. Medical Encyclopedia: Losing weight
★
European Union regulations on nutrition labeling
★ United Kingdom
Food Labelling Regulations 1996 –
Schedule 7: Nutrition labelling
★ United States federal food-labeling regulations
21CFR101.9
★
NIST Special Publication 811, Appendix B8:
calorie.
★ Donatelle, Rebecca J. ''Health: The Basics''. 6th ed. San Francisco: Pearson Education, Inc. 2005.
★
The adoption of joules as units of energy, FAO/WHO Ad Hoc Committee of Experts on Energy and Protein, 1971.
★ Methods used in measuring rate of burn in humans
[1]
External links
★
USDA National Nutrient Database for Standard Reference - Release 19 Official, publicly available reference database and online search site. Includes 7,293 foods and is free to download and use. This database is the one used by most websites that provide calorie information, and forms the basis of the Canadian national nutrient database and others
★
Daily Calorie Calculator