ENAMINE
An 'enamine' is an unsaturated compound derived by the reaction of an aldehyde or ketone with a secondary amine followed by loss of H2O.
If one of the nitrogen substituents is H, it is the tautomeric form of an imine. This usually will rearrange to the imine; however there are several exceptions (such as aniline).
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Form
An analogy may be made between an enol and an ketone or aldehyde and the enamine and an imine.
See also
★ Thorpe reaction
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