
Limonite
'Limonite' is an ore consisting in a mixture of hydrated
iron(III) oxide-hydroxide of varying composition. The generic formula is frequently written as FeO(OH)·nH
2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.
Together with
hematite, it has been
mined as
ore for the production of
iron. Limonite is heavy and yellowish-brown. It is a very common amorphous substance though can be tricky to find when mined with hematite and
bog ore.
It is not a true mineral and it is composed by a mixture of similar
hydrated
iron oxide minerals, mostly
goethite with
lepidocrocite,
jarosite, and others. Limonite forms mostly in or near oxidized iron and other metal ore deposits and as
sedimentary beds. Limonite may occur as the cementing material in iron rich
sandstones. Also known as the Lemon Rock.
It is never
crystallized into macroscopic crystals, but may have a fibrous or microcrystalline structure, and commonly occurs in concretionary forms or in compact and earthy masses; sometimes mammillary,
botryoidal, reniform or stalactitic. The colour presents various shades of brown and yellow, and the streak is always brownish, a character which distinguishes it from hematite with a red, or from magnetite with a black streak. It is sometimes called brown hematite or brown iron ore.

Limonite pseudomorphs after Garnet
Limonite has been known to form
pseudomorphs after other minerals such as
pyrite, meaning that the chemical weathering transforms the crystal of pyrite into limonite but keeps the external shape of the pyrite crystal. It has also been formed from other iron oxides, hematite and magnetite; the carbonate
siderite and iron rich silicates like some
garnets.
It is named from the
Greek word for meadow, in allusion to its occurrence as "
bog-ore" in
meadows and
marshes.
The
hardness is variable, but generally in the 4 - 5.5 range. The
specific gravity varies from 2.9 to 4.3.

Limonite "rind" on goethite?
Uses of limonite
In the past bog ore or brown iron ore were mined as a source of iron. ''Iron caps'' or
gossans of siliceous iron oxide typically forms as the result of intensive
oxidation of
sulfide ore deposits. These gossans were used by prospectors as guides to buried ore. In addition the oxidation of sulfide deposits which contained
gold mineralization often resulted in the concentration of gold in the iron oxide and quartz of the gossans.
Gold bearing limonite gossans were productively mined in the
Shasta County, California mining district. Similar deposits were mined near
Rio Tinto in
Spain and
Mount Morgan in
Australia. In the
Dahlonega gold belt in
Lumpkin County, Georgia gold was mined from limonite rich
lateritic or
saprolite soil. The gold of the primary veins was concentrated into the limonites of the deeply weathered rocks. In another example the deeply weathered iron formations of
Brazil served to concentrate gold with the limonite of the resulting soils.
Limonite from occurrences with consistent color is used as the yellow-brown natural ''earth''
pigment ''
ochre''.
See also
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Bog iron
★
Iron ore
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Ore genesis
★
Peat
External links
★
Abandoned Mine Research & History.
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Mineral galleries
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Mindat
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Gold and limonite