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EspañolSILVER(II) FLUORIDE
(Redirected from Silver difluoride)
'Silver(II) fluoride' is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound. Silver is usually present in its +1 oxidation state. It is used as a fluorinating agent.
AgF2 can be synthesized by fluorinating Ag2O with elemental fluorine. Also, at 200 °C (473 K) elemental fluorine will react with AgF or AgCl to produce AgF2.
As a strong fluorinating agent, AgF2 should be stored in Teflon, a passivated metal container, or a quartz tube. It is light sensitive.
AgF2 can be purchased from various suppliers, the demand being less than 100 kg/year. While laboratory experiments find use for AgF2, it is too expensive for large scale industry use. In 1993, AgF2 cost between 1000-1400 US dollars per kg.
AgF2 is a white crystalline powder, but it is usually black/brown due to impurities. The F/Ag ratio for most samples is < 2, typically approaching 1.75 due to contamination with Ag and oxides and carbon.
For some time, it was doubted silver was actually in the 2+ oxidation state rather in some combination of states such as AgI[AgIIIF4], which would be similar to silver oxide. Neutron diffraction studies, however, confirmed its description as silver(II). The AgI[AgIIIF4] was found to be present at high temperatures, but it was unstable with respect to AgF2.
In the gas phase, AgF2 is believed to have D∞h symmetry.
Approximately 14 kcal/mol (59 kJ/mol) separate the ground and first states. The compound is paramagnetic, but it becomes ferromagnetic at temperatures below −110 °C (163 K).
AgF2 is a strong fluorinating and oxidation agent. Illustrative applications are listed below.
★ Fluoronation and preparation of organic perfluorocompounds
This type of reaction can occur in three different ways (here Z refers to any element or group attached to carbon, X is a halogen):
:1) CZ3H + 2 AgF2 → CZ3F +HF + 2 AgF
:2) CZ3X + 2AgF2 → CZ3F +X2 + 2 AgF
:3) Z2C=CZ2 + 2 AgF2 → Z2CFCFZ2 + 2 AgF
Similar transformations can also be effected using other high valence metallic fluorides such as CoF3, MnF3, CeF4, and PbF4.
★ Fluorinations of aromatic compounds is readily achieved, but selective monofluorinations are more difficult:
:C6H6 + 2 AgF2 → C6H5F + 2 AgF + HF
★ Oxidation of xenon . This reaction, which can be explosive, proceeds in anhydrous HF solutions producing XeF2.
★ AgF2 oxidizes carbon monoxide to carbonyl fluoride.
# Priest, H. F. “Anhydrous Metal Fluorides” Inorganic Syntheses McGraw-Hill: New York, 1950; Vol. 3, pages 171-183.
# ''Encyclopedia of Chemical Technology.'' Kirk-Othermer. Vol.11, 4th Ed. ('1991')
# J.T. Wolan, G.B. Hoflund. "Surface Characterization Study of AgF and AgF2 Powders Using XPS and ISS," ''Applied Surface Science.'' 125, ('1998').
# Hans-Christian Miller, Axel Schultz, and Magdolna Hargittai. "Structure and Bonding in Silver Halides: A Quantum...X=F, Cl, Br, I," Journal of the American Chemical Society 127(22), ('2005').
# Rausch, D.; Davis, r.; Osborne, D. W. "The Addition of Fluorine to Halogenated Olefins by Means of Metal Fluorides," Journal of Organic Chemistry volume 28, pp. 494-497, Jul. ('1962').
# Zweig, A.; Fischer, R. G.; Lancaster, J. "New Methods for Selective Monofluorination of Aromatics Using Silver Difluoride," Journal of Organic Chemistry volume 45, ('1980').
# Levec, J.; Slivnik, J.; Zemva, B. "On the Reaction Between Xenon and Fluorine," ''Journal of Inorganic Nuclear Chemistry'' Volume 36, ('1974').
★ National Pollutant Inventory Fluoride and compounds fact sheet
★ WebElements Silver(II) Fluoride
★ Structure graphic
| Silver(II) fluoride | |
|---|---|
-fluoride-3D-ionic.png) Silver(II) fluoride | |
| General | |
| Systematic name | silver(II) fluoride |
| Other names | silver difluoride |
| Molecular formula | AgF2 |
| Molar mass | 145.865 g/mol |
| Appearance | white or grey crystalline powder, hygroscopic |
| CAS number | 7775-41-9 |
| Properties | |
| Density and phase | 4.58 g/cm3 |
| Solubility in water | Decomposes, violently |
| Melting point | 690 °C (963 K) |
| Boiling point | decomposes at 700 °C (973 K) |
| Structure | |
| Molecular shape | linear |
| Coordination geometry | tetragonally elongated octahedral coordination |
| Crystal structure | orthorhombic |
| Hazards | |
| MSDS | MSDS |
| Main hazards | toxic, reacts violently with water, powerful oxidizer |
| Related compounds | |
| Other silver(II) halides | no other AgX2 stable at room temp. |
| Related compounds | Silver(I) fluoride, AgF Silver subfluoride, Ag2F Silver(II) oxide, AgO Silver(I) oxide, Ag2O |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
'Silver(II) fluoride' is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound. Silver is usually present in its +1 oxidation state. It is used as a fluorinating agent.
| Contents |
| Preparation |
| Composition and structure |
| Uses |
| References |
| External links |
Preparation
AgF2 can be synthesized by fluorinating Ag2O with elemental fluorine. Also, at 200 °C (473 K) elemental fluorine will react with AgF or AgCl to produce AgF2.
As a strong fluorinating agent, AgF2 should be stored in Teflon, a passivated metal container, or a quartz tube. It is light sensitive.
AgF2 can be purchased from various suppliers, the demand being less than 100 kg/year. While laboratory experiments find use for AgF2, it is too expensive for large scale industry use. In 1993, AgF2 cost between 1000-1400 US dollars per kg.
Composition and structure
AgF2 is a white crystalline powder, but it is usually black/brown due to impurities. The F/Ag ratio for most samples is < 2, typically approaching 1.75 due to contamination with Ag and oxides and carbon.
For some time, it was doubted silver was actually in the 2+ oxidation state rather in some combination of states such as AgI[AgIIIF4], which would be similar to silver oxide. Neutron diffraction studies, however, confirmed its description as silver(II). The AgI[AgIIIF4] was found to be present at high temperatures, but it was unstable with respect to AgF2.
In the gas phase, AgF2 is believed to have D∞h symmetry.
Approximately 14 kcal/mol (59 kJ/mol) separate the ground and first states. The compound is paramagnetic, but it becomes ferromagnetic at temperatures below −110 °C (163 K).
Uses
AgF2 is a strong fluorinating and oxidation agent. Illustrative applications are listed below.
★ Fluoronation and preparation of organic perfluorocompounds
This type of reaction can occur in three different ways (here Z refers to any element or group attached to carbon, X is a halogen):
:1) CZ3H + 2 AgF2 → CZ3F +HF + 2 AgF
:2) CZ3X + 2AgF2 → CZ3F +X2 + 2 AgF
:3) Z2C=CZ2 + 2 AgF2 → Z2CFCFZ2 + 2 AgF
Similar transformations can also be effected using other high valence metallic fluorides such as CoF3, MnF3, CeF4, and PbF4.
★ Fluorinations of aromatic compounds is readily achieved, but selective monofluorinations are more difficult:
:C6H6 + 2 AgF2 → C6H5F + 2 AgF + HF
★ Oxidation of xenon . This reaction, which can be explosive, proceeds in anhydrous HF solutions producing XeF2.
★ AgF2 oxidizes carbon monoxide to carbonyl fluoride.
References
# Priest, H. F. “Anhydrous Metal Fluorides” Inorganic Syntheses McGraw-Hill: New York, 1950; Vol. 3, pages 171-183.
# ''Encyclopedia of Chemical Technology.'' Kirk-Othermer. Vol.11, 4th Ed. ('1991')
# J.T. Wolan, G.B. Hoflund. "Surface Characterization Study of AgF and AgF2 Powders Using XPS and ISS," ''Applied Surface Science.'' 125, ('1998').
# Hans-Christian Miller, Axel Schultz, and Magdolna Hargittai. "Structure and Bonding in Silver Halides: A Quantum...X=F, Cl, Br, I," Journal of the American Chemical Society 127(22), ('2005').
# Rausch, D.; Davis, r.; Osborne, D. W. "The Addition of Fluorine to Halogenated Olefins by Means of Metal Fluorides," Journal of Organic Chemistry volume 28, pp. 494-497, Jul. ('1962').
# Zweig, A.; Fischer, R. G.; Lancaster, J. "New Methods for Selective Monofluorination of Aromatics Using Silver Difluoride," Journal of Organic Chemistry volume 45, ('1980').
# Levec, J.; Slivnik, J.; Zemva, B. "On the Reaction Between Xenon and Fluorine," ''Journal of Inorganic Nuclear Chemistry'' Volume 36, ('1974').
External links
★ National Pollutant Inventory Fluoride and compounds fact sheet
★ WebElements Silver(II) Fluoride
★ Structure graphic
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