SUPERHEATING

:''See superheater for the device used in steam engines.''
In physics, 'superheating' (sometimes referred to as 'boiling retardation', or 'boiling delay') is the phenomenon in which a liquid is heated to a temperature higher than its standard boiling point, without actually boiling. This can be caused by rapidly heating a substance while leaving it undisturbed (so as to avoid the introduction of bubbles at nucleation sites).

Contents
Mechanics
Scope restriction
References
See also
External links

Mechanics


Because a superheated liquid is the result of artificial circumstances, it is metastable, and is disrupted as soon as the circumstances abate, leading to the liquid boiling very suddenly and violently (a steam explosion). Superheating is sometimes a concern with microwave ovens, some of which can quickly heat water without physical disturbance. A person agitating a container full of superheated water by attempting to remove it from a microwave could easily be scalded.
Superheating is common when a person puts an undisturbed cup of water into the microwave and heats it. Once finished, the water appears to have not come to a boil. Once the water is disturbed, it violently comes to a boil. This can be simply from contact with the cup, or the addition of substances like instant coffee or sugar, which could result in hot scalding water shooting out. The chances of superheating are greater with smooth containers, such as brand-new glassware that lacks any scratches (scratches can house small pockets of air, which can serve as a nucleation point).
Rotating dishes in modern microwave ovens can also provide enough perturbation to prevent superheating.
There have been some injuries by superheating water, such as when a person makes instant coffee and adds the coffee to the superheated water[1]. This sometimes results in an "explosion" of bubbles. There are some ways to prevent superheating in a microwave oven, such as putting a popsicle stick in the glass, or having a scratched container to boil the water in. However this is very, very rare and can only happen under certain conditions, such as the water having no impurities. Any foreign object in the water, whether it be a spoon or a salt cube, greatly diminishes the chance of an explosion because it provides nucleation sites.
Liquid would not be superheated if the liquid is heated via heated container (e.g. water in a pot on top of a stove) because the heated container surface that heats up the liquid provides nucleation sites for the liquid to boil off and cool down. This is in contrast to a microwave, where the water is directly heated via microwaves and not by the container.

Scope restriction


Milk and water with starch content do not boil over because of superheating, but rather result in extreme foam buildup. This foam is stabilized by special substances in the liquids and therefore does not burst.

References



1. http://www.snopes.com/science/microwave.asp


See also



Supercooling

Supersaturation

Critical point

Microwave oven

Autoclave

Boiling point

External links



Video of superheated water in a microwave explosively flash boiling, why it happens, and why it's dangerous.

A series of superheated water with oil film experiments done in the microwave by Louis A. Bloomfield, physics professor at the University of Virginia. Experiment #13 proceeds with surprising violence.

Video of superheated water in a pot.

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